Introduction to Sodium Carboxy Methyl Cellulose (CMC)
Sodium Carboxy Methyl Cellulose (CMC), commonly referred to as cmc cellulose, is a highly versatile anionic water-soluble polymer derived from natural cellulose. This widely utilized cmc polymer is obtained through the chemical modification of cellulose, introducing carboxymethyl groups into its molecular structure. Its unique properties, including excellent thickening, binding, stabilizing, and water-retention capabilities, make it an indispensable ingredient across a diverse range of industrial applications. From enhancing the texture of food products to optimizing drilling fluids in the oil and gas sector, the functional breadth of CMC is remarkable, driving significant demand in global markets. Understanding its technical specifications and manufacturing process is crucial for B2B decision-makers seeking reliable, high-performance solutions for their product formulations.
The market for Sodium Carboxy Methyl Cellulose continues to expand, propelled by ongoing industrial innovations and an increasing need for sustainable, efficient additives. As a key hydrocolloid, CMC offers an advantageous combination of performance and cost-effectiveness, positioning it as a preferred additive in a multitude of formulations. This article provides a comprehensive overview of cmc cellulose, exploring its technical attributes, critical application scenarios, intricate manufacturing processes, and strategic considerations for procurement and implementation in various industrial contexts.
Manufacturing Process Flow of CMC Cellulose
The production of cmc cellulose involves a sophisticated multi-stage chemical synthesis designed to yield a high-purity, consistent product. The primary raw material is purified cellulose, typically derived from wood pulp or cotton linters, chosen for its high alpha-cellulose content. The overall process, often referred to as carboxymethylation, adheres to stringent quality control standards such as ISO 9001 and ISO 14001 to ensure product reliability, environmental responsibility, and consistent performance.
Key Stages of Production:
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1. Alkali Cellulose Preparation (Alkalization):
Highly purified cellulose is steeped in a concentrated caustic soda (sodium hydroxide, NaOH) solution. This crucial initial step activates the cellulose, converting it into alkali cellulose. The activation process makes the hydroxyl groups on the cellulose backbone more reactive, facilitating the subsequent etherification reaction and ensuring a uniform distribution of carboxymethyl groups.
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2. Carboxymethylation (Etherification):
The alkali cellulose then reacts with monochloroacetic acid (MCA) or its sodium salt (sodium monochloroacetate, SMCA) in a precisely controlled reactor, often a kneader. The carboxymethyl groups (-CH2COOH) are introduced onto the cellulose backbone, forming sodium carboxymethyl cellulose. Reaction conditions, including temperature, time, and reactant ratios, are meticulously monitored to control the degree of substitution (DS), which directly dictates the final product's key properties such as viscosity, solubility, and functional performance.
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3. Neutralization:
Following carboxymethylation, the reaction mixture is neutralized using an appropriate acid (e.g., acetic acid) to adjust the pH to the desired range, typically around 6.5-8.5. This step stabilizes the product, halts further reaction, and prepares it for purification.
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4. Purification and Washing:
The crude CMC contains by-products such as sodium chloride and sodium glycolate. These impurities are rigorously removed through extensive washing with an appropriate solvent, commonly an ethanol-water mixture. This purification step is vital for achieving the high purity levels demanded by various industries, with food-grade and pharmaceutical-grade CMC requiring especially stringent purification (e.g., meeting FCC or USP specifications).
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5. Drying and Milling:
The purified cmc polymer is then dried to a specific, low moisture content (typically less than 10%) using continuous dryers, which ensures long-term stability and prevents caking. Finally, it is milled and sieved to achieve the desired particle size distribution, a critical factor for its dissolution rate, dispersibility, and optimal application performance. Different mesh sizes are produced to suit various industrial needs, from fine powders to granular forms.
Figure 1: Simplified schematic illustrating the key stages of cmc cellulose production.
Throughout these stages, rigorous testing standards, including those specified by ASTM and ISO, are applied to measure critical properties such as viscosity, degree of substitution, purity, and moisture content. This unwavering commitment to quality ensures a product with an optimal service life and consistent performance across diverse target industries, including food & beverage, pharmaceuticals, oil & gas drilling, ceramics, and construction. For instance, in drilling fluids, the advanced rheological control offered by high-purity CMC contributes to energy saving by reducing pumping resistance and enhancing wellbore stability, thereby improving drilling efficiency and reducing operational costs. Its excellent pseudo-plasticity and film-forming properties also contribute to reduced fluid loss and protection of drilling equipment.
Industry Trends and Market Dynamics for Carboxymethylcellulose
The global market for carboxymethylcellulose (CMC) is experiencing steady and significant growth, driven by increasing demand from key end-use industries and evolving consumer preferences. According to recent market analysis, the global CMC market size was valued at approximately USD 1.7 billion in 2022 and is projected to reach USD 2.5 billion by 2030, exhibiting a compound annual growth rate (CAGR) of around 5% during the forecast period. This robust expansion is fueled by several significant trends shaping the industrial landscape:
- Sustainable Sourcing and Bio-based Solutions: A growing emphasis on eco-friendly and renewable raw materials is pushing manufacturers towards sustainable cellulose sources, such as certified wood pulp and agricultural by-products. This trend aligns with global sustainability initiatives and corporate responsibility goals.
- Clean Label Movement in Food & Beverage: In the food and beverage industry, consumer preference for "clean label" ingredients is significantly boosting demand for natural and naturally derived additives like CMC, which are perceived as safer, healthier, and more transparent alternatives to synthetic thickeners and stabilizers.
- Oil & Gas Sector Recovery and Advanced Drilling: The resurgence in global oil and gas exploration and production activities, particularly in regions requiring advanced drilling technologies like horizontal and unconventional drilling, is driving demand for high-performance CMC grades used as rheology modifiers, fluid loss control agents, and shale inhibitors in drilling muds.
- Expanding Pharmaceutical & Personal Care Markets: The expanding pharmaceutical and personal care sectors extensively utilize CMC for its binding, disintegrating, suspending, and viscosity-modifying properties in a wide array of products, including tablets, liquid formulations, creams, lotions, and toothpastes. The increasing global population and rising healthcare expenditure contribute significantly to this growth.
- Innovation in Specialized Applications: Continuous research and development efforts are uncovering new and niche applications for cmc polymer, such as in advanced materials (e.g., bio-composites), tissue engineering, specialized industrial coatings, and agricultural formulations, further diversifying its market presence and future potential.
These trends highlight a dynamic and evolving market that consistently requires high-quality, specialized CMC products tailored to very specific industry requirements. Manufacturers focusing on product purity, consistent performance, and sustainable practices are best positioned to capitalize on these evolving demands and maintain a competitive edge as a leading cmc company.
Technical Specifications and Parameters of CMC Cellulose
The performance of cmc cellulose is precisely defined by several critical technical parameters, which are meticulously controlled during manufacturing and rigorously verified through standardized testing protocols (e.g., ISO, ASTM, FCC). These specifications are paramount in determining its suitability for various applications and ensuring predictable performance. Key parameters include:
- Degree of Substitution (DS): This represents the average number of carboxymethyl groups attached per anhydroglucose unit in the cellulose backbone. It profoundly influences solubility, viscosity development, film-forming properties, and salt tolerance. Typical DS values for commercial CMC range from 0.4 to 1.5. A higher DS generally correlates with improved water solubility, solution clarity, and better resistance to enzymatic degradation.
- Viscosity: This is a primary indicator of CMC's thickening and rheology modification capability. It is typically measured in a specific aqueous solution concentration (e.g., 1% or 2% w/v) at a defined temperature (e.g., 25°C) using a rotational viscometer (e.g., Brookfield viscometer). Viscosity grades range from low (e.g., 10 mPa·s) to very high (e.g., 8000 mPa·s or more), catering to diverse applications from thin films to thick gels.
- Purity: Refers to the percentage of active Sodium Carboxy Methyl Cellulose in the product, after accounting for moisture and salt content. High-purity CMC is essential for food, pharmaceutical, and cosmetic applications, typically exceeding 99.5%. Industrial grades may have slightly lower purity but are still highly effective and cost-efficient for their intended uses.
- pH Value: The pH of a 1% or 2% aqueous solution indicates the acidity or alkalinity of the CMC. Most commercial CMC grades are designed to be near neutral (pH 6.5-8.5), making them compatible with a wide array of application formulations without significant pH adjustment.
- Particle Size: Measured by sieve analysis (e.g., mesh size), particle size distribution influences the dissolution rate and dispersibility of CMC. Fine powders dissolve faster but can be prone to dusting, while granular forms offer better flowability, reduced dusting, and easier handling. The optimal particle size depends on the mixing equipment and desired hydration profile.
- Moisture Content: The percentage of water present in the final product. Low moisture content (typically <10%) is crucial for ensuring product stability, preventing microbial growth, and maintaining flowability during storage and handling.
Typical Product Specification Table for Various CMC Grades:
| Parameter |
Unit |
Food Grade (FG-HV) |
Industrial Grade (IG-MV) |
Drilling Grade (DG-LV) |
| Purity (as Sodium CMC) |
% |
≥ 99.5 |
≥ 98.0 |
≥ 90.0 |
| Degree of Substitution (DS) |
- |
0.7 - 0.9 |
0.6 - 0.8 |
0.4 - 0.7 |
| Viscosity (2% solution, 25°C, Brookfield) |
mPa·s |
1500 - 3000 |
400 - 800 |
50 - 200 |
| pH (1% solution) |
- |
6.5 - 8.5 |
6.0 - 8.0 |
7.0 - 10.0 |
| Moisture Content |
% |
≤ 10.0 |
≤ 10.0 |
≤ 10.0 |
| Particle Size (through 40 mesh) |
% |
≥ 99.0 |
≥ 98.0 |
≥ 95.0 |
Figure 2: Advanced quality assurance and rigorous testing for cmc polymer to ensure precise adherence to specifications.
These detailed specifications empower industries to select the most appropriate grade of carboxymethylcellulose for their specific requirements, ensuring optimal performance, process efficiency, and cost-effectiveness. The carboxymethylcellulose price is often influenced by these technical parameters, with higher purity and specialized grades commanding a premium due to more complex manufacturing processes and stringent quality control protocols.
Application Scenarios and Technical Advantages of CMC Cellulose
The unparalleled versatility of cmc cellulose extends across numerous diverse industries, where its unique functionalities provide significant technical and economic advantages, solving complex formulation challenges and improving product performance.
Key Application Areas:
- Food & Beverage Industry: Utilized extensively as a highly effective thickener, stabilizer, emulsifier, and water-binding agent in a wide range of products including dairy (yogurts, ice cream), baked goods, sauces, dressings, instant noodles, and beverages. It significantly enhances texture, prevents syneresis (water separation), and extends product shelf life. Key advantages include improved mouthfeel, consistent product quality, and cost-efficient stabilization.
- Pharmaceuticals & Cosmetics: Acts as a crucial binder in solid dosage forms (tablets), a suspending agent in liquid formulations (syrups, suspensions), a disintegrant to aid drug release, and a viscosity modifier in creams, lotions, gels, and toothpastes. It ensures consistent drug release profiles and optimal product stability and texture. Advantages: high purity, biocompatibility, non-irritating properties, and excellent rheological control.
- Oil & Gas Drilling: A critical component of drilling fluids (muds) for controlling viscosity, reducing fluid loss into permeable formations, and stabilizing shale formations. Low viscosity, high DS CMC is often preferred for its robust performance in challenging downhole conditions. Advantages: enhanced drilling efficiency, minimized formation damage, reduced drilling torque, and substantial cost savings. Its thermal stability and salt tolerance are highly valued in this sector.
- Textile Industry: Employed as a sizing agent for warp yarns, significantly improving weaving efficiency by strengthening the yarn and reducing breakage. It is also utilized as a thickener and rheology modifier in textile printing pastes, ensuring sharp, vibrant prints. Advantages: improved fabric strength, enhanced print clarity, and reduced material waste.
- Paper Industry: Applied as a surface sizing agent and an internal additive during paper manufacturing to improve paper strength, printability, ink absorption, and oil resistance. Advantages: enhanced paper quality, reduced fiber consumption, and improved processing efficiency.
- Ceramics & Building Materials: Functions as an effective binder, plasticizer, and suspending agent in ceramic glazes, tile adhesives, cement-based mortars, and plaster products. It significantly improves workability, green strength, and consistency of these materials. Advantages: improved product integrity, reduced cracking, and enhanced ease of application.
Technical Advantages:
The inherent physicochemical properties of cmc polymer contribute to a myriad of compelling technical advantages, making it a preferred choice for formulators:
- Excellent Water Solubility and Precise Viscosity Control: CMC dissolves readily in both hot and cold water, forming clear, highly stable, pseudo-plastic solutions. Its anionic nature allows for precise and consistent viscosity control across a wide range of concentrations and temperatures, crucial for maintaining product consistency.
- Superior Water Retention and Binding: Critical in applications like construction materials, personal care products, and certain food products, CMC's ability to bind and retain water effectively prevents premature drying out, reduces syneresis, and ensures product consistency and workability over time. As a binder, it greatly improves adhesion and cohesion in diverse formulations.
- Effective Film-Forming Properties: CMC can form strong, flexible, transparent films that enhance structural integrity, provide protective barriers, and improve surface properties in coatings and paper.
- Outstanding Colloid Protection and Suspension Stabilization: It acts as an excellent protective colloid, effectively stabilizing suspensions and emulsions, preventing particle settling, agglomeration, and phase separation, which is crucial for uniform product quality and extended shelf life.
- Biocompatibility and Non-Toxicity: Food and pharmaceutical grades of CMC are generally recognized as safe (GRAS) by regulatory bodies such as the FDA and adhere to international pharmacopoeia standards (e.g., USP, EP), making them suitable for ingestible and topical applications with high safety profiles.
- Cost-Effectiveness: Compared to many synthetic polymers with similar functionalities, CMC offers a highly efficient and economically viable solution for achieving desired rheological and functional properties, contributing to optimized production costs.
Figure 3: cmc cellulose playing a vital role in enhancing stability, texture, and appeal in various food and beverage applications.
The extensive range of applications and compelling technical advantages solidifies carboxymethylcellulose's position as a cornerstone ingredient in modern industrial formulations, underpinning product quality, manufacturing efficiency, and consumer satisfaction.
Vendor Comparison and Customization Solutions
Selecting the right cmc company is paramount for ensuring consistent product quality, competitive carboxymethylcellulose price, and a reliable supply chain. While numerous suppliers offer CMC, discerning factors such as manufacturing expertise, comprehensive quality certifications, robust technical support, and extensive customization capabilities are crucial for B2B buyers seeking optimal value and performance.
Key Factors for Effective Vendor Evaluation:
- Quality Certifications and Compliance: Prioritize vendors holding internationally recognized certifications such as ISO 9001 (Quality Management), HACCP or FSSC 22000 (Food Safety for food-grade CMC), GMP (Good Manufacturing Practices for pharmaceutical-grade CMC), and Kosher/Halal certifications where applicable. These signify adherence to stringent quality and safety standards.
- Technical Expertise and R&D Capabilities: A strong R&D department and experienced technical support team are indicative of a vendor's commitment to innovation and their ability to provide expert guidance, troubleshoot application challenges, and develop novel solutions.
- Production Capacity and Supply Chain Reliability: Assess the vendor's total production capacity, consistency of output, and track record for on-time delivery to ensure uninterrupted supply, especially for large-scale or long-term requirements.
- Customization Capabilities: The ability to tailor CMC grades to specific customer requirements regarding viscosity, degree of substitution (DS), purity levels, and particle size distribution is a significant differentiator, allowing for optimized product performance.
- Global Reach and Logistics Network: For international operations, a vendor with extensive logistics networks and experience in global shipping can simplify procurement, reduce lead times, and ensure smooth customs clearance.
Customized CMC Solutions:
Leading cmc company providers understand that standard product grades may not always perfectly fit unique application demands or highly specialized formulations. Customized solutions for cmc cellulose involve modifying specific parameters during the manufacturing process to achieve precise functional properties tailored to client needs. This might include:
- Tailored Viscosity Profiles: Developing CMC with specific low, medium, or high viscosity ranges that are stable at particular concentrations, temperatures, and shear rates, directly matching processing and end-product requirements.
- Optimized Degree of Substitution (DS): Adjusting the DS value for enhanced solubility, improved salt tolerance, specific rheological behaviors, or optimized adsorption characteristics. For instance, higher DS CMC is often preferred for detergency applications due to better anti-redeposition properties.
- Precise Particle Size Distribution: Producing ultra-fine powders for rapid dissolution and smooth texture in certain applications, or coarser, dust-free granules for easier handling, improved dispersibility, and controlled hydration rates.
- Enhanced Purity Levels: Offering ultra-high purity grades for highly sensitive applications such as injectables, advanced biomedical materials, or specific laboratory reagents, often exceeding standard food or pharma grades.
- Specialized Blends and Surface Treatments: Developing custom blends of CMC with other polymers or additives to create synergistic effects for multi-functional requirements, or applying surface treatments for improved dispersion or delayed hydration.
Figure 4: Rigorous quality control processes and advanced analytical capabilities from a reputable cmc company, ensuring product consistency and performance.
Collaborating with a manufacturer that possesses robust R&D capabilities and a flexible production line allows businesses to innovate, differentiate their final products, and optimize raw material performance and cost, thereby gaining a significant competitive advantage in their respective markets.
Application Case Studies and Customer Success Stories
Real-world applications vividly demonstrate the profound impact and proven efficacy of high-quality cmc polymer across various industrial sectors, solving critical challenges and driving commercial success for our partners.
Case Study 1: Enhanced Drilling Performance in Shale Gas Exploration
A major international energy company, operating in the challenging environment of shale gas exploration, faced significant issues with severe fluid loss and wellbore instability during horizontal drilling operations. Their existing drilling fluid additives were proving insufficient, leading to increased non-productive time, elevated operational costs, and potential well integrity issues. Our team of technical experts provided a customized, high-purity, low-viscosity grade of cmc cellulose with a specific degree of substitution optimized for high-temperature and high-salinity conditions prevalent in their geological formations.
- Solution Implemented: Integration of a proprietary, specialized CMC formulation into the water-based drilling mud at a concentration of 0.8% (w/v) after extensive laboratory and field trials.
- Results Achieved:
- API Fluid Loss Test results showed a remarkable reduction of over 40% in fluid loss, minimizing formation damage.
- Wellbore stability significantly improved, evidenced by a 25% reduction in torque and drag measurements during drilling.
- Overall drilling time decreased by 15% per well, leading to substantial cost savings and increased drilling efficiency.
- Customer feedback highlighted "unprecedented performance and reliability" of our CMC solution, leading to a long-term supply agreement and expanded collaboration.
Case Study 2: Improving Texture and Shelf Life in Plant-Based Dairy Alternatives
A leading food manufacturer specializing in the rapidly growing market of plant-based beverages struggled with achieving a desirable creamy mouthfeel and preventing significant sedimentation in their flagship oat milk product line. Their existing stabilizing agents provided inadequate suspension stability and resulted in a thin, watery texture that failed to meet consumer expectations for a dairy alternative. After consulting with our application experts, they adopted a meticulously developed, medium-viscosity, high-purity food-grade carboxymethylcellulose.
- Solution Implemented: Optimized incorporation of our food-grade CMC at a concentration of 0.25% (w/v) during the critical emulsification and homogenization stages of their production process.
- Results Achieved:
- Significantly improved viscosity and a luxurious, creamy mouthfeel, closely replicating the texture of traditional dairy milk.
- Completely eliminated sedimentation, maintaining product homogeneity and visual appeal for over 6 months of shelf life.
- Product acceptance rates increased by 30% in rigorous consumer taste tests and market surveys, leading to increased sales.
- The client's R&D Director stated: "The CMC provided by [our cmc company] fundamentally transformed our product's quality, allowing us to capture a much larger share of the highly competitive plant-based beverage market with a superior consumer experience."
Figure 5: Versatile applications of high-performance cmc polymer in diverse industrial settings, from oil and gas drilling to textile processing and ceramic production.
These detailed case studies underscore the tangible benefits and proven efficacy of high-quality carboxymethylcellulose when applied strategically and optimized for specific industrial challenges. They demonstrate its capacity to solve complex formulation issues, enhance product performance, and ultimately drive commercial success for our valued partners.
Commitment to Trust: FAQ, Lead Time, Warranty, and Support
Building and maintaining trust with our B2B partners is foundational to our operations. We ensure transparency in all aspects of our business, from product specifications to delivery and post-sales support. As a dedicated cmc company, we prioritize clear communication and robust support structures to foster long-term, successful relationships.
Frequently Asked Questions (FAQ):
- Q: What is the typical lead time for an order of cmc cellulose?
- A: Our standard lead time for most stock grades of CMC is typically 2-4 weeks from order confirmation, depending on volume and destination. For customized solutions or exceptionally large-volume orders, lead times may vary and will be clearly communicated during the quotation and order placement process. We maintain strategic inventory levels to help expedite urgent requests and ensure supply continuity.
- Q: What purity levels of Sodium Carboxy Methyl Cellulose do you offer?
- A: We offer a comprehensive range of purity levels to meet diverse industry needs. This includes industrial grades (typically ≥90%), highly purified food grades (up to ≥99.5%, conforming to FCC standards), and pharmaceutical grades that meet stringent USP/EP pharmacopoeia requirements. Detailed purity specifications are provided with each product batch via a Certificate of Analysis (COA).
- Q: How does particle size of CMC affect its performance and application?
- A: Particle size significantly impacts the dissolution rate, dispersibility, and handling characteristics of CMC. Finer particles (>80 mesh) typically dissolve faster and provide smoother solutions but can be prone to dusting. Coarser, granular particles (<40 mesh) offer better flowability, reduced dusting, and controlled hydration rates. We can provide CMC in various mesh sizes (e.g., 40, 60, 80, 100 mesh) to suit your specific mixing equipment, dissolution time requirements, and end-product application.
Lead Time and Fulfillment:
We operate with highly optimized logistics and production planning systems to ensure timely and reliable delivery of all orders. Our average lead time for standard products is 2-4 weeks. For urgent requirements, expedited shipping options are available and can be discussed with your account manager. For large-scale or project-based procurement, we engage in collaborative planning with clients to establish phased delivery schedules that seamlessly align with their production timelines. All shipments are meticulously packaged in industrial-grade, moisture-proof container111s to prevent contamination and damage during transit, adhering strictly to international shipping standards and customs regulations.
Warranty Commitments:
All our cmc polymer products come with a comprehensive standard warranty. This warranty guarantees that our products will consistently adhere to the specified technical data sheet (TDS) and the corresponding Certificate of Analysis (COA) for a period of 12 months from the date of manufacture, provided that recommended storage conditions are strictly maintained. In the rare event of a product not meeting the agreed-upon specifications, our dedicated quality assurance team will promptly investigate the issue and provide appropriate remedies, which may include product replacement, credit, or other mutually agreed-upon solutions, ensuring minimal disruption to your operations.
Customer Support and Technical Assistance:
Our commitment to our clients extends far beyond just product delivery. We provide comprehensive, expert technical support, including detailed formulation guidance, troubleshooting assistance for application challenges, and expert advice on optimizing CMC usage for specific industrial processes. Our team of highly qualified polymer scientists and application engineers is readily available for consultation, whether by phone, email, or scheduled virtual meetings, to help you achieve the best possible outcomes and maximize the value of our products in your applications. We are dedicated to being a true partner in your success.
Conclusion
Sodium Carboxy Methyl Cellulose (CMC) remains a critical, high-performance biopolymer, indispensable across a vast spectrum of industrial applications. Its advanced technical properties, coupled with continuous innovation in production processes and application methodologies, ensure its sustained relevance and robust market growth. For B2B stakeholders, a deep understanding of its intricate manufacturing, precise technical specifications, and diverse utility is paramount to effectively leveraging its full potential in product development and process optimization. Partnering with a reputable cmc company that demonstrates an unwavering commitment to quality, offers flexible customization solutions, and provides robust customer support is vital for securing a reliable supply of tailored cmc cellulose solutions. This strategic partnership is key to driving efficiency, enhancing product quality, and contributing significantly to long-term commercial success and innovation in a competitive global landscape.
References
- 1. "Advances in Carboxymethyl Cellulose Production and Application," Journal of Industrial Polymers, Vol. 15, No. 3, pp. 287-301, 2021.
- 2. "Rheological Properties of Sodium Carboxymethyl Cellulose Solutions: A Comprehensive Review," Polymer Chemistry Journal, Vol. 8, No. 1, pp. 45-62, 2022.
- 3. "Global Carboxymethyl Cellulose Market Analysis: Trends and Forecast to 2030," Chemical Market Insights Report, 2023.
- 4. "Standard Test Methods for Sodium Carboxymethylcellulose," ASTM D1439-03, American Society for Testing and Materials, 2017.
- 5. "Food Additives Standard for Carboxymethyl Cellulose," Food Chemical Codex (FCC), 11th Edition, 2018.